When two p orbitals share electrons in a covalent bond and the interaction is
not symmetrical about a line between the two nuclei, the result is a pi bond. Here
is an example:
Chapter 14 gives more examples of sigma and pi bonding.
PROPERTIES OF IONIC SUBSTANCES
Laboratory experiments reveal that, in general, ionic substances are characterized
by the following properties:
- In the solid phase at room temperature they do not conduct appreciable
electric current. - In the liquid phase they are relatively good conductors of electric current.
The conductivity of ionic substances is much smaller than that of metallic
substances. - They have relatively high melting and boiling points. There is a wide
variation in the properties of different ionic compounds. For example,
potassium iodide (KI) melts at 686°C and boils at 1,330°C, while
magnesium oxide (MgO) melts at 2,800°C and boils at 3,600°C. Both KI and
MgO are ionic compounds. - They have relatively low volatilities and low vapor pressures. In other
words, they do not vaporize readily at room temperature. - They are brittle and easily broken when stress is exerted on them.