The acid–base systems are summarized below.
Type
Acid
Base
Arrhenius
H + or H 3 O+ producer
OH – producer
Brønsted-Lowry
proton (H +) donor
proton (H +) acceptor
Lewis
electron-pair acceptor
electron-pair donor
Acid Concentration Expressed as pH
Frequently, acid and base concentrations are expressed by means of the pH
system. The pH can be defined as −log [H+], where [H+] is the concentration of
hydrogen ions expressed in moles per liter. The logarithm is the exponent of 10
when the number is written in the base 10. For example:
REMEMBER
pH = −log[H+]
The logarithms of more complex numbers can be found in a logarithm table.
An example of a pH problem is:
Find the pH of a 0.1 molar solution of HCl.
1st
step.
Because HCl ionizes almost completely into H+ and Cl
−, [H+] = 0.1 mole/liter.
2nd
step.
By definition
pH = −log [H+]
so