Limiting Reactants
When reactants are mixed, they are seldom added in the exact stoichiometric proportions as shown
in the balanced equation. Therefore, in most reactions, one of the reactants will be used up first.
This reactant is known as the limiting reactant (or limiting reagent) because it limits the amount of
product that can be formed in the reaction. The reactant that remains after all of the limiting
reactant is used up is called the excess reactant.
TEST STRATEGY
If the quantities of two reactants are given, be on the lookout for the possibility that one of
them is a limiting reactant.
Example: If 28 g of Fe reacts with 24 g of S to produce FeS, what would be the limiting
reactant? How many grams of excess reactant would be present in the vessel at the
end of the reaction?
Solution: First, the balanced equation needs to be determined. We are told that Fe and S
come together to form FeS:
Fe + S → FeS
This is already balanced.
Next, the number of moles for each reactant must be determined.