SAT Subject Test Chemistry,10 edition

(Marvins-Underground-K-12) #1
Note    that    (NH 3 ) 2   implies N 2 H 6 :   2   atoms   of  N   and 6   atoms   of  H.

12 . C 4 H 9


The reaction    is  of  the form:

hydrocarbon +   O 2     →   CO 2    and H 2 O
We can see that all the carbon and all the hydrogen on the product side have to come from the
hydrocarbon originally, and so from the amounts of CO 2 and H 2 O given, the moles of carbon
and hydrogen in the hydrocarbon can be calculated.

Since   each    mole    of  CO 2    contains    one mole    of  carbon, 1.33    moles   of  CO 2    contains    1.33    moles   of
carbon. Therefore, the hydrocarbon contains 1.33 moles of carbon.

Since   one mole    of  H 2 O   contains    two moles   of  hydrogen    atoms,  1.5 moles   of  H 2 O   contains    3.0
moles of hydrogen. Therefore, the hydrocarbon contains 3 moles of hydrogen.

Using   these   calculations,   the simplest    formula that    can be  written is  C1.33H 3 .  However,
empirical and molecular formulas are not expressed with decimals or fractions, so these
coefficients should be multiplied by their least common multiple to get whole-number
coefficients. Both 1.33 and 3 are multiplied by 3 to give an empirical formula of C 4 H 9.

13 . The following are the correct balanced equations.

Free download pdf