SAT Subject Test Chemistry,10 edition

(Marvins-Underground-K-12) #1

(the two possible sequences share the same initial state and the same final state), the change in
enthalpy will be the same.


Example: Given  the following   thermochemical  equations:

Solution: Equations a,  b,  and c   must    be  combined    to  obtain  equation    d.  Since   equation    d   contains    only    C,  H 2 ,   and C 3 H 8 ,   we
must eliminate O 2 , CO 2 , and H 2 O from the first three equations. Equation a is reversed to get C 3 H 8 on the product side.

e)

(Note   that    when    we  reverse the reaction,   the sign    of  the enthalpy    change  is  reversed    as  well.)

Next,   equation    b   is  multiplied  by  3   (this   gives   equation    f)  and c   by  4   (this   gives   equation    g). The following   addition    is
done to obtain the required equation d: 3b + 4c + e.

f)

a)

b)

Calculate   ΔH  for the reaction:

c)

d) 3C   (graphite)  +   4H 2    (g) →   C 3 H 8     (g)
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