88 ENVIRONMENTALENGINEERING
BOD concentration might be low. Engineers often talk of “pounds of BOD,” a value
calculated by multiplying the concentration by the flow rate, with a conversion factor,
so that
The BOD of most domestic sewage is about 250 ma, while many industrial wastes
run as high as 30,OoOmg/L. The potential detrimental effect of untreated dairy waste
that might have a BOD of 20,000 mg/L is quite obvious.
As discussed in Chapter 4, the BOD curve can be modeled using Eq. (4.8):
BOD(t) = Lo(1 - e-kjr),
where
BOD(t) = amount of oxygen required by the microorganisms at any time t
(ma),
LO = ultimate carbonaceous oxygen demand (mg/L),
k’, = deoxygenation rate constant (days-’), and
t = time (days).
When it is necessary to know both k’, and LO, as when modeling the dissolved oxygen
profile in a stream, both are measured using laboratory BOD tests.
There are a number of techniques for calculating k; and h. One of the simplest is
a method devised by Thomas (1950). Rewriting Eq. (4.8) using common logarithms
results in
BOD(t) = Lo(1 - 10-k;f),
which can be rearranged to read
(&) ‘I3 = (2.3 k’, + (5.10)
This equation is in the form of a straight line
x=a+bt,
where x is (r~~oD(t)>‘/~, the intercept (a) is (2.3k’,Lo)-’I3, and the slope (b) is
k; 213/(3 .43L:l3).
By plotting BOD versus r, the slope (b) and intercept (a) can be used to solve for
ki andh:
k’, = 2.61 (Ha)
Lo = 1/(2.3k’,a3).