Encyclopedia of Environmental Science and Engineering, Volume I and II

(Ben Green) #1

GROUNDWATER RESOURCES 445


the destruction of the ecological system and natural resources
but also present a danger to public health. Pollutants have
been broadly classified into eight categories by the U.S.
Public Health Service.


  1. Oxygen-demanding wastes: These include domes-
    tic and industrial wastewaters, leachates from land-
    fill, and any other wastes containing biodegradable
    organic material. These wastes are stabilized by
    microorganisms and will remove dissolved oxygen
    from water.

  2. Infective agents: Bacteria, virus, protozoa, and
    other infectious agents may be present in domes-
    tic wastewaters. Those that reach drinking water
    or even recreational waters represent a health
    hazard to humans.

  3. Plant nutrients: Mineral substances, particularly
    nitrates and phosphates, stimulate the growth of
    plants. However, nitrates in groundwater poten-
    tially infiltrating through heavily fertilized soil
    can be a public health hazard.

  4. Organic chemicals: Chemicals such as insecti-
    cides, pesticides, and detergents are toxic at low
    concentrations and can cause significant changes
    in groundwater quality.

  5. Other minerals and chemicals: This group con-
    sists primarily of materials found in industrial
    wastes, including chemical residues, petrochemi-
    cals, salts, acids, etc. New chemical substances are
    being created at the rate of 400 to 500 compounds
    per year. Many of these substances are known to
    be toxic, although very little is known about their


biological action. Almost nothing is known about
the possible long-term effects of these chemical
compounds.


  1. Sediments from land erosion: These materials
    have little effect on groundwater quality since
    they would be filtrated out in the first stages of
    percolation.

  2. Radioactive substances: Expected increases in
    the use of nuclear reactors for power generation
    indicate that radioactivity may be a serious prob-
    lem in the future. The extremely long half-lives of
    some radioactive materials make the disposal of
    radioactive wastes difficult. Once a radionuclide
    reaches the groundwater it remains a hazard for
    a long time. One rule is that a radionuclide is no
    longer dangerous after nine half-lives.^

  3. Heat: Heat from industry and power generation
    is considered a serious pollutant. Its effect on
    groundwater is limited to reducing the value of a
    groundwater source for cooling water.


In addition to the eight categories of pollutants used by
the U.S. Public Health Service, oil can be considered a ninth
category, since oil spills in coastal waters have found their
way into groundwater supplies near the coast.
The quality of water required for industrial-process
usages varies widely with the type of industry and the
type of process used. For example, the recommended total
solids concentration in boiler feed waters varies from 50 to
3,000 mg/l depending on the design of the boiler and the pres-
sure of operation. The quality of water used for agricultural
operations also varies considerably. Range-cattle-use water

Rainwater contains dissolved
organics and minerals, suspended
particles, virus, bacteria

Rainwater

Biological Action
Sedimentation

Filtration Ion
Exchange

Aerobic Zone
Biological Action
Removal of Organics Oxidation of NH 3

Filtration Ion Exchange

Rock Strata

Groundwater

FIGURE 6 Effect of water movement on water quality.

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