Encyclopedia of Environmental Science and Engineering, Volume I and II

(Ben Green) #1

872 PCBs AND ASSOCIATED AROMATICS


FIGURE 14 Di-ortho-chlorobiphenyls.

TABLE 12
Data from Larsen et al., Gordon and Breach 1993. (Ref. 155).

PCB # A1232 A1242 A1248 A1254 A1260 A1262 Askarel

60 0.46 0.66 1.32 0.56 0.011 0.027 0.039
74 0.86 1.37 2.65 1.77 0.023 0.061 0.070
77 — 0.50 0.30 ND ND — —
81 — ND — ND ND — —
105 0.17 0.43 1.00 4.71 0.045 0.0079 0.32
114 0.0080 0.0098 0.019 0.043 0.0014 0.0003 0.0011
118 0.32 0.74 1.69 9.09 0.57 0.25 1.94
123 0.024 0.038 0.085 0.33 ND ND ND
126 0.0013 0.0037 0.011 0.027 0.0004 ND ND
156 0.059 0.026 0.083 1.07 0.48 0.59 0.56
157 0.0013 0.0026 0.011 0.026 0.024 0.0078 0.085
167 ND ND 0.0014 0.045 0.030 0.017 0.059
169 ND ND ND ND ND ND ND
189 ND ND 0.012 0.031 0.13 0.052 0.077

COMPOUNDS OF CONCERN

In 1968 a group of workers at Kyushu University in northern
Japan determined that a group of patients with acneiform
eruptions similar to chloracne had ingested contaminated
rice oil used in cooking. The symptoms of the poisoning

suggested that it was due to organochlorine compounds. The
word “Yusho” or “rice oil” disease is used to describe the
incident. The number of recognized victims over a period of
about ten years rose to a total of approximately 1800 people.
The rice oil contamination was determined to be
Kanechlor 400 which was produced as an approximately

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