Encyclopedia of Environmental Science and Engineering, Volume I and II

(Ben Green) #1

922 PCBs AND ASSOCIATED AROMATICS


TABLE 46
Combustion and Pyrolysis Products of PCB Replacement Fluids

Trade Names Primary Components Combustion Products Pyrolysis Products

Wemcol
Edisol II
Edisol III

Selectrol
Dielektrol

Aue et al. (1969, 1972) showed the applicability of
surface-bonded silicones to adsorb PCBs from water.
Extraction methods for PCBs from soil, sediment, sludge
and paper have used more polar solvents or solvent mix-
tures than that used for the analysis of water. Holden (1970),
for example, used a mixture of hexane and isopropanol to
extract PCBs from sewage sludge.
PCBs from non-carbon copy paper were extracted with
acetone in a Soxhlet apparatus for 3 days (Kuratsune and
Masuda, 1972).

PCB extraction from biological samples tends to be
complicated by problems of incomplete extraction, cleanup
losses etc. Extraction techniques have most often used
Soxhlet extraction to conserve the volume of solvent or a
percolation system with large volumes of solvent to obtain
satisfactory recovery efficiency. Soxhlet extraction was used
by Zitko (1972) in the extraction of tissue samples using
100 mL of hexane in a 1 hour extraction. Acker (1970) used
a combination of solvents passed through a tissue sample
homogenized with sea sand and packed into a column. The

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