Physical Chemistry Third Edition

(C. Jardin) #1

E Classical Mechanics 1273


Taking the time derivatives of Eqs. (E-28) and (E-29), we can write the Lagran-
gian as

L

1

2

m 1

(

.

xc−

m 2

.

x
M

) 2

+

1

2

m 2

(

.

xc+

m 1

.

x
M

) 2

−V(x)



1

2

m 1



.

xc
2
− 2 m 2

.

xc

.

x
M

+

(

m 2

.

x
M

) 2 ⎤

⎦+^1

2

m 2



.

x
2
c+^2 m^1

.

xc

.

x
M

+

(

m 1

.

x
M

) 2 ⎤

⎦−V(x)

(E-30)

The terms containing

.

xc

.

xcancel, so that

L

1

2

(m 1 +m 2 )

.

x
2
c+

1

2

m 1 m 2 (m 1 +m 2 )
M^2

.

x
2
−V(x)



1

2

M

.

x^2 c+

1

2

μ

.

x^2 −V(x) (E-31)

Thereduced massof the pair of particles is denoted byμand is defined by

μ

m 1 m 2
m 1 +m 2



m 1 m 2
M

(E-32)

The kinetic energy is

K 

1

2

M

.

x
2
c+

1

2

μ

.

x
2
(E-33)

Since the variables are separated in the Lagrangian, we obtain separate equations of
motion forxcandx:

M

d

.

xc
dt



∂L

∂xc

 0 (E-34)

μ

d

.

x
dt



∂L

∂x

−

dV
dx

(E-35)

If there are no external forces, the center of mass of the two particles moves like a
particle of massMthat has no forces acting on it, while the relative coordinate changes
like the motion of a particle of massμmoving at a distancexfrom a fixed origin
and subject to the potential energyV(x). The motion of two particles moving in the
xdirection has been separated into two one-body problems. The motion in theyand
zdirections is completely analogous, so that in three dimensions we can assert:The
fictitious particle of massμmoves around the origin of its coordinate in the same way
that particle 1 moves relative to particle 2, while the center of mass moves like a free
particle of massM.
The separation is the same in Hamiltonian mechanics. In three dimensions, the
kinetic energy is

K 

1

2

M(

.

x
2
c+

.

y
2
c+

.

z
2
c)+

1

2

μ(

.

x
2
+

.

y
2
+

.

z
2
) (E-36)
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