Physical Chemistry Third Edition

(C. Jardin) #1

11


The Rates of Chemical Reactions


PRINCIPAL FACTS AND IDEAS


  1. The rate of a chemical reaction depends on the concentrations of the
    reactants and products and on the temperature.

  2. The rate law of a chemical reaction is the differential equation for the rate
    of change of the concentration of a reactant or product as a function of
    concentrations of reactants and products.

  3. Rate laws can be determined experimentally using the method of initial
    rates.

  4. The rate laws for some reactions can be integrated to obtain integrated
    rate laws.

  5. Experimental data on concentrations can be compared with integrated
    rate laws to determine the experimental rate law.

  6. In a simple case it is possible to integrate the rate law for a reaction with a
    non-negligible reverse reaction.

  7. Two consecutive reactions constitute a simple mechanism for a chemical
    reaction, and the rate law can be integrated for a simple case.

  8. Specialized techniques exist for studying fast reactions.


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