131where is the Langevin function. For we can
expand (S.4.36.3) to obtainSince andwe have for thedielectric constant4.37 Two-Dipole Interaction (Princeton)
Introducesphericalcoordinates with the axis along theline of thesepa-
rationbetween the dipoles.Then the partitionfunctionreadsThe potential energy of the interaction can berewritten in the form
Since
(S.4.37.2)becomesTHERMODYNAMICS AND STATISTICAL PHYSICS