The Chemistry Maths Book, Second Edition

(Grace) #1

262 Chapter 9Functions of several variables


One of the principal uses of the total differential in the physical sciences is in the


formulation of the laws of thermodynamics (see Examples 9.22 and 9.27). In the


following sections we use (9.16) and its limiting form (9.17) to derive a number of


differential and integral properties of functions.


9.6 Some differential properties


The total derivative


In the function of two variables,z 1 = 1 f(x, y), let xand ybe functions of a third


variable t:


x 1 = 1 x(t), y 1 = 1 y(t) (9.19)


Thenz 1 = 1 f(x(t), y(t))is essentially a function of the single variable t, and there exists


an ordinary derivativedz 2 dt. This derivative is called the total derivativeof zwith


respect to t, and can be obtained directly by substituting the functionsx(t)andy(t)


for the variables inf(x,y)and differentiating the resulting function of t. It can also be


obtained indirectly, by dividing the expression (9.16) by ∆tand taking the limit


∆t 1 → 10. Thus, division of


by ∆tgives


(9.20)


and, in the limit∆t 1 → 10 ,


(9.21)


Alternatively, the same result is obtained by dividing the total differential (9.17) by


(infinitesimal) dt.


Equation (9.21) is a generalization of the chain rule (see Section 4.6). For a function


of nvariables,u 1 = 1 f(x


1

,x


2

,x


3

,1=,x


n

), in which the variables are all functions of t,


(9.22)


=












=


i

n

i

i

u


x


dx


dt


1

du


dt


u


x


dx


dt


u


x


dx


dt


=






























1

1

2

2

+












u


x


dx


dt


n

n

dz


dt


z


x


dx


dt


z


y


dy


dt


yx


=

















































z


t


z


x


x


t


z


y


y


t


yx


∆≈










∆+










z ∆


z


x


x


z


y


y


yx

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