The Chemistry Maths Book, Second Edition

(Grace) #1

266 Chapter 9Functions of several variables


(9.28)


the equation can also be written as


(9.29)


This form is sometimes called the ‘−1 rule’.


The presence of the – sign in equations (9.27) and (9.29) sometimes causes unease,


but it can be explained geometrically. Thus, for the particular z-surface shown in


Figures 9.3 and 9.6 the slopes along the xand ydirections are both negative at P (the


gradient lines slope ‘downward’), so that (∂z 2 ∂x)


y

and (∂z 2 ∂y)


x

are negative and their


quotient in equation (9.27) is positive. However, Figure 9.6 shows that for motion


along the contour from P to Q, ∆yis necessarily positive but ∆xnegative (or vice versa


for motion Q to P) so that (∂y 2 ∂x)


z

is negative. Hence the – sign. Similar considerations


apply to the other three possible pairs of signs of the slopes.


We note that the distinction between dependent and independent variables has


disappeared from equations (9.26) to (9.29); any one variable can be regarded as a


function of the other two. We note also that whereas (9.26) is readily generalized for


sets of more than three variables, equations (9.27) and (9.29) are true for only three


variables at a time (all others being kept constant).


EXAMPLES 9.15


(i) Givenz 1 = 1 x


2

y


3

, find


By equation (9.27),


(ii) For , find




=,




=,










=−


r


x


x


r


r


y


y


r


y


x


x


y


r


and


r


y


x










.
rxy=+

( )


22

12/

zyx


y


x


z


x


z


y


xy


x










=−


















=−


2


3


3

222

2


3


y


y


x


=−


yx


z


x


xy


z


y


xy










=,










23 =


322

z


y


x










.


−=


























1


zxy


x


y


y


z


z


x


yy


z


x


x


z










=










1

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