The Chemistry Maths Book, Second Edition

(Grace) #1

13 Second-order


differential equations.


Some special functions


13.1 Concepts


We saw in Sections 12.5 to 12.7 how three very different physical problems are


modelled in terms of the samedifferential equation: equation (12.35) for the classical


harmonic oscillator as an initial value problem, the same equation, (12.47), for the


quantum-mechanical particle in a box as a boundary value problem, and (12.62) for


the quantum-mechanical particle in a ring as a periodic boundary value problem.


This is a common phenomenon in the mathematical modelling of physical systems,


and a number of equations are important enough to have been given names. Some of


these are listed in Table 13.1.


Table 13.1


Name Equation


Legendre (1 1 − 1 x


2

)y′′ 1 − 12 xy′ 1 + 1 l(l 1 + 1 1)y 1 = 10


Associated Legendre (1 1 − 1 x


2

)y′′ 1 − 12 xy′ 1 + 1 [l(l 1 + 1 1) 1 − 1 m


2

2 (1 1 − 1 x


2

)]y 1 = 10


Hermite y′′ 1 − 12 xy′ 1 + 12 ny 1 = 10


Laguerre xy′′ 1 + 1 (1 1 − 1 x)y′ 1 + 1 ny 1 = 10


Associated Laguerre xy′′ 1 + 1 (m 1 + 111 − 1 x)y′ 1 + 1 (n 1 − 1 m)y 1 = 10


Bessel x


2

y′′ 1 + 1 xy′ 1 + 1 (x


2

1 − 1 n


2

)y 1 = 10


The equations in Table 13.1 are all second-order homogeneous linear equations with


non-constant coefficients, and they have particular solutions that play an important


role in the mathematics of the physical sciences. These solutions are often called


special functions.


The standard methods used to solve the equations in Table 13.1 and many other


linear differential equations in the sciences are the power-series method, described


in Section 13.2, and the more general Frobenius method, outlined in Section 13.3.


The former is used in Section 13.4 to obtain the physically-significant particular


solutions of the Legendre equation. These solutions are called Legendre polynomials


and they occur whenever a physical problem in three dimensions is formulated


in terms of spherical polar coordinates. Subsequent sections are devoted to brief


descriptions of the other special functions that are solutions of the equations listed


in Table 13.1.

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