The Chemistry Maths Book, Second Edition

(Grace) #1

390 Chapter 13Second-order differential equations. Some special functions


17.Find the Legendre polynomialP


6

(x)(i)by means of the recurrence relation (13.21),


(ii)from the general expression (13.19) forP


l

(x).


18.Use the formula (13.24) to find the associated Legendre functions (i)P


1

1

, (ii)P


4

m

(x)for


m 1 = 1 1, 2, 3, 4. Express the functions in terms ofcos 1 θ 1 = 1 xandsin 1 θ 1 = 1 (1 1 − 1 x


2

)


122

.


19.Show that (i)P


1

is orthogonal toP


4

andP


5

,(ii)P


2

is orthogonal toP


0

andP


3

.


20.Show thatP


2

1

is orthogonal toP


1

1

andP


1

4

.


Section 13.5



  1. (i)Use the series expansion (13.31) to findH


5

(x). (ii)Verify by substitution in (13.30)


thatH


5

(x)is a solution of the Hermite equation. (iii)Use the recurrence relation (13.33)


to findH


6

(x).


22.Sketch the graph of the Hermite functione


−x

2

22

H


3

(x).


Section 13.6



  1. (i)Use the power series method to find a solution of the Laguerre equation (13.38).


(ii)Show that this solution reduces to the polynomial (13.39) when nis a positive integer


or zero and when the arbitrary constant is given its conventional value n!.


24.FindL


4

(x)(i)from equation (13.39), (ii)fromL


2

(x)andL


3

(x)by means of the


recurrence relation (13.41).


Section 13.7



  1. (i)Find the Bessel functionJ


2

(x)(i)from the series expansion (13.50); (ii)fromJ


0

(x)


andJ


1

(x)by means of the recurrence relation (13.56).


26.Use the recurrence relation (13.56) to findJ


522

(x)andJ


− 522

(x).


27.Confirm that the spherical Bessel functionj


l

(x)satisfies equation (13.60).

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