29.11Lifetime and Line Width
Now we have computed the lifetime of a state. For some atomic, nuclear, or particle states, this
lifetime can be very short. We know that energy conservation can be violated for short times
according to the uncertainty principle
∆E∆t≤̄h
2.
This means that a unstable state can have an energy width on the order of
∆E≈
̄hΓtot
2.
We may be more quantitative. If the probability to be in the initial state is proportional toe−Γt,
then we have
|ψi(t)|^2 =e−Γt
ψi(t)∝e−Γt/^2ψi(t)∝e−iEit/ ̄he−Γt/^2We may take the Fourier transform of this time function to the the amplitude as a function of
frequency.
φi(ω) ∝∫∞
0ψi(t)eiωtdt∝
∫∞
0e−iEit/ ̄he−Γt/^2 eiωtdt=
∫∞
0e−iω^0 te−Γt/^2 eiωtdt=
∫∞
0ei(ω−ω^0 +iΓ 2 )t
dt=
[
1
i(ω−ω 0 +iΓ 2 )ei(ω−ω^0 +iΓ
2 )t]∞
0
=i
(ω−ω 0 +iΓ 2 )We may square this to get the probability or intensity as a function ofω(and henceE= ̄hω).
Ii(ω) =|φi(ω)|^2 =1
(ω−ω 0 )^2 +Γ
2
4This gives the energy distribution of an unstable state. It is calledthe Breit-Wigner line shape.
It can be characterized by its Full Width at Half Maximum (FWHM) of Γ.
The Breit-Wigner will be the observed line shape as long as the densityof final states is nearly
constant over the width of the line.