A Guidebook to Mechanism in Organic Chemistry

(Barry) #1

Carbanions and Their Reactions


H H
</ O O
-*• I II -> II
Me—C C=0 Me—C C==0 Me—C—CH,+ CO,

(XL1X)

Confirmation of this mode of decarboxylation of the free acid has been
obtained by 'trapping' the acetone-enol intermediaHWfXLIX).

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