274 ENGINEERING THERMODYNAMICS
dharm
/M-therm/th5-4.pm5
Note that if in this problem sA – s 2 happened to be greater than sA – s 1 , this would mean that
s 1 was greater than s 2 , and the process should appear as in Fig. 5.36.
Note. The change of entropy can also be found by using the following relation :
s 2 – s 1 = cv
n
n
−
−
F
HG
I
KJ
γ
1 loge^
T
T
2
1
= 0.718
25 399
25 1
−
−
F
HG
I
KJ loge^
597.3
873
F
HG
I
KJ Qγ= = =
L
N
M
O
Q
P
c
c
p
v
- (^005) 1.
0718
399
.
= 0.718 × (– 0.596) × (– 0.3795) = 0.1626 kJ/kg K (increase).
Example 5.28. In an air turbine the air expands from 7 bar and 460°C to 1.012 bar and
160 °C. The heat loss from the turbine can be assumed to be negligible.
(i)Show that the process is irreversible ;
(ii)Calculate the change of entropy per kg of air.
Solution. Refer Fig. 5.37.
Initial pressure, p 1 = 7 bar = 7 × 10^5 N/m^2
Initial temperature, T 1 = 460 + 273 = 733 K
Final pressure, p 2 = 1.012 bar = 1.012 × 10^5 N/m^2
Final temperature, T 2 = 160 + 273 = 433 K
Fig. 5.37
(i)To prove that the process is irreversible :
Since the heat loss is negligible, the process is adiabatic.
For a reversible adiabatic process for a perfect gas, using the following equation, we have :
T
T
2
1 =
p
p
2
1
1
F
HG
I
KJ
−γ
γ
T 2
733 =
1.4
012 1.4
7
1
F
HG
I
KJ
F −
HG
I
KJ