134 CHAPTER 3. CHARGE TRANSPORT IN MATERIALS
σn[cm-2]
Trap
Figure 3.23: Picture of the capture cross section
Case 1
vth x 0
Case 2 ΔL 2
ΔL 2
ΔL 3
ΔL 3
Path in the
absence of trap
Figure 3.24: Electrons within the “volume” above will be captured by the trap
closer) would have intersected the capture cross section and be captured. Hence all electrons
in the volumeV =σn·vthwill be captured each second by available empty traps. Thus the
number of electrons available to be captured per second is
nσnvth (3.8.25)
and recalling the concentration of available empty traps isNt(1−f), then the rate,racan be
written:
ra=vthσnnNt(1−f) (3.8.26)
OR, the proportionality constant isσnvth(for the rate of electron capture)
vth=
√
2 E
m∗
=
√
2 ·
3 kBT
2 m∗