150 CHAPTER 4. JUNCTIONS IN SEMICONDUCTORS:P-NDIODES
where the subscriptsnandprefer to then-side andp-side of the device. Using the Boltzmann
approximation for the Fermi level (see equation 2.4.4)
(Ec−EF)n=−kBTln(nno
Nc)
wherennois the electron density on then-side of the device. Assuming that all of the donors
are ionized,
nno=Nd
Similarly,
(EF−Ev)p=−kBTln(
pp 0
Nv)
whereppois the hole density on thep-side and is given by
pp=NaThis gives the built-in voltage
eVbi=Eg+kBTln(nn 0 pp 0
NcNv)
Using the relation for intrinsic carrier density
n^2 i=NcNvexp(
−
Eg
kBT)
we get
Vbi=kBT
eln(nn 0 pp 0
n^2 i) (4.2.3)
Ifnn 0 andnp 0 are the electron densities in then-type andp-type regions, the law of mass action
(i.e., the productnpis constant) tells us that
nn 0 pn 0 =np 0 pp 0 =n^2 i (4.2.4)This gives for the built-in potential,Vbi=Vn−Vp(figure 4.3)Vbi=kBT
elnpp 0
pn 0(4.2.5)
or
Vbi=kBT
elnnn 0
np 0(4.2.6)
We have the following equivalent expressions:
pp 0
pn 0= exp (eVbi/kBT)=nn 0
np 0