546 APPENDIX E. BEYOND THE DEPLETION APPROXIMATION
This is called the Gummel correction to the built-in voltage. To apply the depletion approxima-
tion and calculate parameters related to electrostatics such as depletion region width, depletion
capacitance etc., it is necessary to substituteV
′
biforVbiin previous formulae. Hence,
W=
√
2 s
e
(
1
NA
+
1
ND
)
(Vbi′) (E.3)
note that in a Schottky barrier the correction due to the thermal broadening of carriers (which
occurs over a Debye Length,LD) occurs in only the semiconductor and hence
V
′
bi=Vbi−
kBT
e
for a Schottky barrier.
The Gummel correction is arrived at by solving Poisson’s equation in the depletion region in-
cluding the contribution of mobile charges. Consider the band diagram of ap-njunction in
figure E.3. For the purpose of our analysis we will only consider thep-type semiconductor. The
analysis is equivalent for then-side. The governing equations are
d^2 Ψ
dx^2
=−
ρ(x)
(P oisson′sequation) (E.4)
and
ρ(x)=q(ND+−NA−+pp−np) (E.5)
whereND+andNA−are the ionized donors and acceptors respectively with the latter dominant
in thep-region. In the bulk of the semiconductor charge neutrality requiresρ(x)=0or from
equation E.5
ND+−NA−=np 0 −pp 0 (E.6)
Applying equation E.6 to equation E.5 and equation E.4 we get the resultant Poisson’s equation
d^2 Ψ
dx^2
=−
e
[(pp−pp 0 )−(np−np 0 )] (E.7)
From Boltzmann statistics and figure E.3 we knowpp=pp 0 e−
keΨ
BTandnp=np 0 e+
keΨ
BTor
d^2 Ψ
dx^2
=−
e
[
pp 0 (e−
keΨ
BT−1)−np 0 (e+
keΨ
BT−1)
]
(E.8)
Recognizing that
(∂Ψ
∂x
)
d
(∂Ψ
∂x
)
=∂
(^2) Ψ
∂x^2 dΨwe can integrate equation E.8 from the bulk towards
the junction
∫∂∂xΨ
0
(
∂Ψ
∂x
)
d
(
∂Ψ
∂x
)
=−
e
∫Ψ
0
[
pp 0 (e−
keΨ
BT−1)−np 0 (e+
keΨ
BT−1)
]
dΨ (E.9)
UsingE=−∂x∂Ψwe get
E=
(
2 kBT
pp 0
[(
e−
keΨ
BT+ eΨ
kBT
− 1
)
+
np 0
pp 0
(
e−
keΨ
BT− eΨ
kBT