An Introduction to Environmental Chemistry

(Rick Simeone) #1
between seawater and basaltic ocean crust. However, estimates of the element
fluxes involved in these processes are uncertain, mainly because representative
sampling in these remote environments is difficult and expensive. The flux
estimates are based on a few studies at individual sites on the East Pacific and
Mid-Atlantic ridges (Fig. 6.16). Global fluxes have been calculated from these
sites, using various geophysical and geochemical approaches. A major problem
however, still to be resolved, is a rigorous quantification of the amount of
hydrothermal activity occurring at high temperatures near the ridge axis, versus
lower temperature circulation on the ridge flanks (Fig. 6.14 & Table 6.5). This
is important, because temperature affects the degree, rate and even direction of
some chemical reactions. Despite these problems, for some elements the direc-
tion of the fluxes agree from site to site allowing construction of tentative global
fluxes (Table 6.2). We should, however, note that the magnitudes of the fluxes in
Table 6.2 are uncertain.
In the following section we describe the effects of hydrothermal activity
on major ions in the oceans: the effects on minor components in the oceans are
discussed in Sections 6.5.2 and 6.5.5.

The Oceans 211

0 °

30 °

30 °

60 °S

60 °N

CarlsbergRidge
Red
Sea
iR
dg
e

Chil
eR
ise

Lau/Valu FA

N. Fiji Basin

Woodlark
Basin

Manus Basin

Marina Trough

Okinawa
Trough

Escanaba
Trough
EPR 10–21°N
EPR 3.5°S

Southeast
Indian Ridge

Endeavor
Cleft

Tag

Rainbow

Lucky
Strike

Steinaholl
Azores

Ridge

120 ° 150 ° 180 ° 150 ° 120 ° 90 ° 60 ° 30 ° 0 ° 30 ° 60 ° 90 °

Kairei

Guyamus
Basin

Explorer, Juan de
Fuca, and Gorda Ridges

Pacif
icAntarc
ticR

idg
e

aE
ts
Pa

cif

ic
Ris

e
Galapagos
EPR
17–19°S

East Scotia
Ridge

Mid
Atlantic

Snake Pit/Mark

Broken Spur

Asal Rift
Central
Indian
Ridge

Sou
thw

est
Indi
an
Ridg

e

Knipovich

Gakkol Ridge

Edmond

Mid-ocean Ridge
Subduction zone
Hydrothermal vent sites

Fig. 6.16Location of known mid-ocean ridge hydrothermal systems in the oceans. After Baker et al. (1995).

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