Organic Chemistry of Explosives

JWBK121-IND October 17, 2006 21:46 Char Count= 0

Index 369

5-azidotetrazole 344
aziridines

carbamate derivatives 227

reactions with dinitrogen pentoxide 114,

226–7, 361

ring-opening nitration of 226–7, 361

3,3′-azobis(6-amino-1,2,4,5-tetrazine) (DAAT)

322–3

azotetrazole

dihydrazinium salt 316

salts 315–16

Bachmann process (for HDX/RDX) 244–5, 247,

248, 249

Bamberger rearrangement 145–7, 203, 341

benzofurazan, nitro derivatives 302

benzofuroxans, nitro derivatives 303–7

benzotriazene-1-oxide 314

benzotriazoles, nitro derivatives 313–14

benzotrifuroxan 303

bicyclic 1,3-dinitramines, synthesis 222

bicyclic nitramines and derivatives 271–3

bicycloalkanes, polynitro derivatives 82–5

bicyclo[3.3.1]nonane, polynitro derivatives 85

bicyclo[3.3.0]octane, polynitro derivatives 84–5
4,6-bis(3-amino-5-nitro-1H-1,2,4-triazole-1-yl)-

5-nitropyrimidine (DANTNP) 310

2,4-bis-(5-amino-3-nitro-1,2,4-

triazolyl)pyrimidine (IHNX) 310

N,N′-bis(3-aminopicryl)-1,2-ethanediamine 165

bis(2-azidoethyl) adipate 334

bis(2-azidoethyl)nitramine 335

3,3-bis(azidomethyl)oxetane (BAMO) 113, 337

2,2-bis(azidomethyl)-1,3-propanediol dinitrate

(PDADN) 337

3,4-bis(N,N-difluoroamino)-1,2-butanediol

dinitrate 106

1,4-bis(N,N-difluoroamino)-2,3-butanediol

dinitrate 106

3,3-bis(difluoroamino)octahydro-1,5,7,7-

tetranitro-1,5-diazocine (TNFX) 271

bis(2,2-dinitropropyl)acetal (BDNPA) 2, 11, 48

bis(2,2-dinitropropyl)formal (BDNPF) 2, 11

bis(2,2-dinitropropyl)hydrazine 44

bis(fluorodinitroethyl)amine 335

1,1-bis(2-fluoro-2,2-dinitroethyl)ethyl acetal 34

bis(2-fluoro-2,2-dinitroethyl)formal (FEFO) 2,

48

bis(furazano)piperazine 301–2

1,3-bishomopentaprismane, polynitro derivatives
79

3,6-bis(hydrazino)-1,2,4,5-tetrazine 323

2,2-bis(hydroperoxy)propane 340

1,1-bis(hydroxymethyl)-nitroethane 108

bis-nitramines 283

1,3-bis(2-nitroxyethylnitramino)-2,4,6-

trinitrobenzene 115

4,4′-bis(picrylamino)-3,3′-bifurazan (BPABF)

299

2,6-bis(picrylamino)-3,5-dinitropyridine (PYX)

317

3,4-bis(picrylamino)furazan (BPAF) 300

2,6-bis(picrylazo)-3,5-dinitropyridine (PADP)

317

1,3-bis(1,2,4-triazol-3-amino)-2,4,6-

trinitrobenzene (BTATNB/SDATO) 166,

308

N,N′-bis(1,2,4-triazol-3-yl)-4,4′-diamino-

2,2′,3,3′,5,5′,6,6′-octanitrobenzene

(BTDAONAB) 128, 177, 308

bis(2,2,2-trinitroethyl)amine 43

bis(2,2,2-trinitroethyl)formal 48

bis(2,2,2-trinitroethyl)urea (DiTeU) 43

boron trifluoride hydrate/potassium nitrate,

O-nitration with 96

brisance of explosives, meaning of term xxvi

3-(bromomethyl)-1-azabicyclo[1.1.0]butane, in

synthesis of TNAZ 266

1-bromo-2,3,4,6-tetranitrobenzene 156

BSX 255

BTX 313–14

BuNENA 199 , 200, 283, 361

butanediol dinitrates 95, 100

1,2,4-butanetriol trinitrate (BTTN) 88

tert-butylamines, nitrolysis of 218–20

N-tert-butyl-3,3-dinitroazetidine, in synthesis of

TNAZ 266, 268

n-butyl nitrate 96

N-butyl-2-nitroxyethylnitramine (BuNENA) 199 ,

200, 283, 361

butyltetryl 242

caged structures

adamantanes 79–82

bicycloalkanes 82–5

cubanes 71–4

cyclobutanes and derivatives 69–71

cyclopropanes 68–9

as energetic materials 67–8

homocubanes 74–8

isowurtzitanes 193, 200, 273–5

nitrate esters incorporated into 112