Organic Chemistry of Explosives

JWBK121-IND October 17, 2006 21:46 Char Count= 0

Index 371

3,5-diamino-2,4,6-trinitrotoluene (DATNT) 170
diazides 335

1,4-diazidobutane 333

1,3-diazido-2,2-dimethylpropane 333

1,3-diazidopropane 333

1,3-diazido-2-propanol 335

1,7-diazido-2,4,6-trinitro-2,4,6-triazaheptane

(DATH) 282

diazo oxides 146, 340–3

1,5-diazocines,N-nitro andN-nitroso derivatives

216, 269–71

2-diazo-4,6-dinitrophenol (DDNP / DINOL) 146,

340, 342

4-diazo-2,6-dinitrophenol 341

2-diazo-3-methyl-4,6-dinitrophenol 342

diazonium phenolates 146, 340–3

diazonium salts, with nitrite anion, aromatic

nitration with 148–9

diazophenols 146, 340–3

nitro-substituted 341

synthesis 146–7, 340–3

via diazotization of aminophenols 340–1

via rearrangement ofo-nitroarylnitramines

146, 341–3

dibenzotetraazapentalenes 324–6
di-iso-butylnitramine 225

di-n-butylnitramine 216

1,3-dichloro-2,4,6-trinitrobenzene (styphnyl

chloride) 172

1,4-dideoxy-1,4-dinitro-neo-inositol

dinitrate ester (LLM-101) 93

tetranitrate ester 92–3

Diels–Alder reactions, polynitroalkenes 51

trans-1,2-diethyl-1,2-dinitrocyclopropane,

synthesis 68

diethylene glycol bis(azidoacetate) ester

(DEGBAA) 324

diethylene glycol dinitrate (DEGDN) 88, 91

3-(N,N-difluoroamino)-1,2-propanediol dinitrate

106

diisocyanates 239

1,3-dimethoxybenzene, tri-nitration of 173

N,N-dimethylaniline, nitration of 241

2,3-dimethyl-2,3-dinitrobutane, synthesis 14,

32

trans-1,2-dimethyl-1,2-dinitrocyclopropane,

synthesis 68

3,4-dimethyl-3,4-dinitrohexane, synthesis 32

3,7-dimethyl-1,5-dinitro-1,3,5,7-

tetraazacyclooctane 236
dimethyldioxirane (DMDO)

amino-to-nitro group conversion with 149,

154–5

isocyanates oxidised by 23–4

dimethylnitramine, synthesis 232

dimethylolnitramine 249, 253–4

3,8-dimethyl-2,4,7,9-tetranitro-4,7-diazadecane

235

dinitramide

ammonium salt 212, 284, 285, 286

N-guanylurea salt 285

dinitramide anion 284–6, 363

compared with alkylN,N-dinitramines 285

synthetic routes 285–6, 363–4

N,N-dinitramino group 286–7

dinitraminobutanes 232

dinitraminopropanes 232

1,2-dinitrate esters 102, 360

1,3-dinitrate esters 102–3, 107, 360

vic-dinitrate esters 6, 99–101, 105

1,3-dinitrates 102–3

gem-dinitrates 94

dinitroacetonitrile, ammonium salt 49

gem-dinitroaliphatic compounds, synthesis

10–11, 24–7

α,ω-dinitroalkanes

bis-methylol derivatives 25, 45

reactions 46

synthesis 8, 28, 29

1,3-dinitroalkanes 40

gem-dinitroalkanes 10–12, 15, 16, 25, 31, 40, 105

vic-dinitroalkanes 32, 105

4,4′-dinitro-3,3′-azobis(furazan) (DNAzBF) 299

1,1′-dinitro-3,3′-azo-1,2,4-triazole (C-DNAT) 311

4,4′-dinitro-3,3′-azo-1,2,4-triazole (N-DNAT)

311

4,4′-dinitro-3,3′-azoxybis(furazan) (DNABF) 299

dinitrobenzenes 154

4,6-dinitrobenzofuroxan (DNBF) 304

1,3-dinitrobicyclo[1.1.1]pentane 69

4,4′-dinitro-3,3′-bifurazan 299

N,N′-dinitro-N,N′-bis(2-hydroxyethyl)oxamide

dinitrate (NENO) 114, 193 , 194, 210

N,N′-dinitro-N,N′-bis(2-hydroxyethyl)sulfamide

dinitrate 210

5,5′-dinitro-4,4′-bis(1,2,3-triazole) (DNBT) 312

1,4-dinitrobutane 29

2,4-dinitrochlorobenzene 136

1,3-dinitrocubane 24, 72

1,4-dinitrocubane 23–4, 72

dinitrocyanoacetic acid esters 16

1,3-dinitrocyclobutane 70