1.3. Radioactivity and Radioactive Decay 11
α-decay: Qα=(MX−MY−Mα)c^2
β-decay: Qβ=(MX−MY)c^2
HereMstands for atomic mass, which means thatMαis the mass of the helium
atom and not the helium nucleus as in case of equation 1.3.A.
Example:
Determine if actinium-225 can decay throughαas well asβmodes.
Solution:
Theαdecay reaction for actinium-225 can be written as
225
89 Ac→
221
87 Fr+
4
2 He.
TheQ-value, in terms ofatomic masses, for this reaction is
Qα =(MAc−MFr−Mα) 931. 502
= (225. 023229 − 221. 014254 − 4 .002603) 931. 502
=5. 93 MeV.
If actinium went throughβdecay, the decay equation would be written as
225
89 Ac→
225
90 Th+e,
with aQ-value, in terms ofatomic masses,givenby
Qβ =(MAc−MTh) 931. 502
= (225. 023229 − 225 .023951) 931. 502
= − 0. 67 MeV.
Since theQ-value is positive forαdecay therefore we can say with confidence
that actinium-225 can emitαparticles. On the other hand a negativeQ-value
forβdecay indicates that this isotope can not decay through electron emission.
1.3.B TheDecayEquation.......................
Radioactive decay is a random process and has been observed to follow Poisson
distribution (see chapter on statistics). What this essentially means is that the rate
of decay of radioactive nuclei in a large sample depends only on the number of
decaying nuclei in the sample. Mathematically this can be written as
dN
dt
∝−N
or
dN
dt
= −λdN. (1.3.12)
HeredN represents the number of radioactive nuclei in the sample in the time
windowdt.λdis a proportionality constant generally referred to in the literature as