1.3. Radioactivity and Radioactive Decay 15
Since half life represents the time taken by half of the atoms in a sample to
decay, we can simply replaceNbyN 0 /2 in equation 1.3.13 to get
1
2
= e−λdT^1 /^2
eλdT^1 /^2 =2
T 1 / 2 =
ln(2)
λd
=ln(2)τ=0. 693 τ.
Example:
The half life of a radioactive sample is found to be 45 days. How long would
it take for 2 moles of this material to decay into 0.5 mole.
Solution:
SinceT 1 / 2 = 45 days, therefore
λd =
ln(2)
T 1 / 2
=
ln(2)
45
=15. 4 × 10 −^3 day−^1.
Since moleMis proportional to the number of atoms in the material, therefore
equation 1.3.13 can also be written in terms of number of moles as follows.
M=M 0 e−λdt
Rearrangement of this equation gives
t=
1
λd
ln
(
M 0
M
)
.
Hence the time it will take for 1.5 moles of this material to decay is
t =
1
15. 4 × 10 −^3
ln
(
2. 0
0. 5
)
≈ 90 days.
1.3.C CompositeRadionuclides
A problem often encountered in radioactivity measurements is that of determining
the activity of individual elements in a composite material. A composite material
is the one that contains more than one radioisotope at the same time. Most of the
radioactive materials found in nature are composite.
Let us suppose we have a sample that contains two isotopes having very different
half lives. Intuitively thinking, we can say that the semilogarithmic plot of activity