BIOINORGANIC CHEMISTRY A Short Course Second Edition

INDEX 491

cytochrome b(6)f and, 132
cytochrome bc 1 and, 132, 168 –169
ferredoxin and, 21, 24, 455
FeS 4 centers, 135t
Fe 2 S 2 centers, 135t, 168
cytochrome b(6)f and, 22, 383–384,
385f, 386–387, 387t
cytochrome bc 1 and, 22, 389–391,
393, 395, 397, 399, 401, 403, 406f,
405–407
Fe 3 S 4 centers, 135t, 137–139
Fe 4 S 4 centers, 135t
Mössbauer spectroscopy, 137–139,
454–455
nitrogenase and, 137–139
rubredoxin and, 22, 24, 135t, 455
Iron-sulfur proteins (ISP), see also
Rieske iron sulfur protein
aconitase, 21, 44, 132, 454–458
cytochrome b(6)f and, 22, 132, 383–
384, 385f, 386–387, 387t
cytochrome bc 1 , 168–169, 389–391,
393, 395, 397, 399, 401, 403, 406f,
405–407
ferredoxin and, 21, 24, 455
nitrogenase, and, 137–139
rubredoxin and, 22, 24, 135t, 455
Isoelectric focusing (IEF), 40 –41
Isoleucine (Ile, I), 31f, 34, 34f, 324, 346,
350 –351, 416, 427
Isomer shift, see Mössbauer
spectroscopy
Isozymes, 44

Jahn-Teller effects, 10 –11, 18, 126, 163,
178
J values, see nuclear magnetic
resonance

KAR-2, 311–313, 311f
K inetics, 8 –13, 143 –14 6
associative, 10
dissociative, 12
fi rst-order, 9–11
fl ash photolysis, 144–146
interchange mechanism, 12
Marcus theory, 25–26
psuedo-fi rst-order conditions, 9–10
rate laws and rate constants, 11–13

second order, 11–12

stopped fl ow, 143 –14 4

Kinetics, enzyme, 43– 47

Michaelis-Menten, 13, 45– 47, 326

KM, 45–46, 46f

KML, 8–9, 9t

Lability, 10, 23f

Lanthanide ions, 14

EPR and, 125

lanthanide-based energy transfer

(LRET), 223–224

NMR probes, 103

Lead (Pb), 2, 2t, 7, 7t

Least-squares method, 90, 165

Leucine (Leu, L), 31f, 57f, 58, 64, 324,

346, 350–351

Lewis bases, 19

Library of Congress, as information

resource, 183

Ligand exchange rates, 10–11, 11t

water exchange rates, 11t

Ligand fi eld stabilization energies

(LFSE), 11, 15, 18

Ligand fi eld theory, 11, 18

Ligand-metal charge transfer (LMCT),

81, 450, 459

Ligand preference, 3, 6, 4t, 5t, 6t, 8,

9–10, 9t, 47, 55, 347f, 356 –357,

359

Lineweaver-Burk plot, 46, 46f

Lithium (Li), 2, 171, 190t, 193, 199, 211,

283–284, 287, 290–291

L-stereoisomers, 32

Lumen, 96, 301

Ca2+-ATPase and, 327–329, 328f,

330f, 333–337

cytochrome b(6)f and, 385–386, 385f

cytochrome c and, 410 – 411, 415

Lyases, 45, 116

Magnesium (Mg), 1, 2t, 7t, 9–10, 9t, 11t,

47, 138, 141, 189, 197, 197t

ATP complexes, 44, 47

catalytic RNA and, see ribozymes

cytochrome c oxidase and, 436f

homeostasis and, 191t, 192–193, 195,

197t

structure and triggers, 4t