12.11A OVERALL SUMMARY OF REDUCTION REACTIONS (SECTION 12.3)
(^) NaBH 4 LiAlH 4
Aldehydes C
O
R H C
OH
R
H
H
C
OH
R
H
H
Ketones C
O
R R' C
OH
R
H
R'
C
OH
R
H
R'
Esters C
O
— C
OH
R
H
R OR' H + HOR’
Carboxylic
acids C
O
— C
OH
R
H
R OH H
Hydrogens in blue are added during the reaction workup by water or aqueous acid.
12.11B OVERALL SUMMARY OF OXIDATION REACTIONS (SECTION 12.4)
Reactant PCC H 2 CrO 4 KMnO 4
1° alcohols C
OH
R
H
H
C
O
RH C
O
ROH C
O
ROH
2° alcohols^ C
OH
R
H
R'
C
O
RR' C
O
RR' C
O
RR'
3° alcohols C
OH
R
R"
R'
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