Advices For Studying Organic Chemistry

(Wang) #1

2.13 SUMMARY OF IMPORTANT FAMILIES OF ORGANIC COMPOUNDS


Table 2.3 Important Families of Organic Compounds

Family example Specific IUPAC name Common name General formula Functional group
Alkane CH 3 CH 3 Ethane Ethane RH C–C bond C–H and

Alkene CH 2 =CH 2 Ethane Ethylene

RCH=CH 2
RCH=CHR
R 2 C=CHR
R 2 C=CR 2

C C

Alkyne HC CH Ethyne Acetylene HCRC≡≡CR CR CC
Aromatic
Benzene Benzene ArH Aromatic ring

Haloalkane CH 3 CH 2 Cl Chloroethane Ethyl chloride RX C X

Alcohol CH 3 CH 2 OH Ethanol Ethyl alcohol ROH C OH

Ether CH 3 OCH 3 Methoxy-methane Dimethyl ether ROR C O C

Amine CH 3 NH 2 Methanamine Methylamine

RNH 2
R 2 NH
R 3 N

C N

Aldehyde CH
3 CH

O
Ethanal Acetaldehyde RCHO
C

O
H
Ketone CH 3 CCH 3
C

O O
Propanone Acetone RCOR' CC

Carboxylic
acid CH 3 COH

O
Ethanoic acid Acetic acid RCOOH
C

O
OH

Ester CH 3 C
C

O
OCH O

O
3 Methyl ethanoate Methyl acetate RCOOR' C

Ethanamide Acetamide

CH 3 CONH 2
CH 3 CONHR’
CH 3 CONR’R” C

Amide CH 3 CNHO 2 O N
Nitrile H 3 CCN Ethanenitrile Acetonitrile RCN CN
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