Advices For Studying Organic Chemistry

(Wang) #1

The oscillating electric and magnetic fields of a beam of ordinary light in one plane.
The waves depicted here occur in all possible planes in ordinary light.


2.16B Theory:


  1. Wavenumber (ν):
    ν (cm–1) = λ (cm)^1 ν (Hz) = νc (cm) = c^ (cm/sec)λ (cm)^


cm–1 = (^1 μ) x 10,000 and μ = (^) (cm^1 - (^1) ) x 10,000


* the wavenumbers (ν) are often called "frequencies".



  1. THE MODES OF VIBRATION AND BENDING:
    Degrees of freedom:
    Nonlinear molecules: 3N–6
    linear molecules: 3N–5


vibrational degrees of freedom
(fundamental vibrations)
* Fundamental vibrations involve no change in the center of gravity of the molecule.


  1. “Bond vibration”:


A stretching vibration
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