The oscillating electric and magnetic fields of a beam of ordinary light in one plane.
The waves depicted here occur in all possible planes in ordinary light.
2.16B Theory:
- Wavenumber (ν):
ν (cm–1) = λ (cm)^1 ν (Hz) = νc (cm) = c^ (cm/sec)λ (cm)^
cm–1 = (^1 μ) x 10,000 and μ = (^) (cm^1 - (^1) ) x 10,000
* the wavenumbers (ν) are often called "frequencies".
- THE MODES OF VIBRATION AND BENDING:
Degrees of freedom:
Nonlinear molecules: 3N–6
linear molecules: 3N–5
vibrational degrees of freedom
(fundamental vibrations)
* Fundamental vibrations involve no change in the center of gravity of the molecule.
- “Bond vibration”:
A stretching vibration