Advices For Studying Organic Chemistry

(Wang) #1
Doublydegenerate

Scissoring (bending) Scissoring (bending)
(δs CO) (δs CO)
666 cm–1 (15.0 μm) 666 cm–1 (15.0 μm)
resolved components of bending motion
and indicate movement perpendicular to the plane of the page



  1. AX 2 :


Stretching Vibrations

Symmetrical stretching Asymmetrical stretching
(νs CH 2 ) (νas CH 2 )


Bending Vibrations

In-plane bending or scissoring Out-of-plane bending or wagging
(δs CH 2 ) (ω CH 2 )


In-plane bending or rocking Out-of-plane bending or twisting
(ρs CH 2 ) (τ CH 2 )

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