Organic Chemistry

(Jacob Rumans) #1

Overview of addition, elimination, substitution and rearrangement reactions


108.4 Substitution reactions


This involves the exchange of one group for another.


AB + CD → AC + BD

Common reaction types include



  • radical reactions and

  • nucleophilic substitutions

    • SN1, Unimolecular nucleophilic substitution

    • SN2, Bimolecular nucleophilic substitution




108.5 Rearrangement reactions


A molecule shifts or otherwise rearranges to form a different molecule.


A → B

This typically happens when one molecule changes into an isomer of itself.

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