to imagine that the two phases are mixed well, forming a homogeneous
mixture (Fig. 3–35). Then the properties of this “mixture” will simply be
the average properties of the saturated liquid–vapor mixture under consider-
ation. Here is how it is done.
Consider a tank that contains a saturated liquid–vapor mixture. The vol-
ume occupied by saturated liquid is Vf, and the volume occupied by satu-
rated vapor is Vg. The total volume Vis the sum of the two:
Dividing by mtyields
since xmg/mt. This relation can also be expressed as
(3–4)
where vfgvgvf. Solving for quality, we obtain
(3–5)
Based on this equation, quality can be related to the horizontal distances
on a P-vor T-vdiagram (Fig. 3–36). At a given temperature or pressure, the
numerator of Eq. 3–5 is the distance between the actual state and the satu-
rated liquid state, and the denominator is the length of the entire horizontal
line that connects the saturated liquid and saturated vapor states. A state of
50 percent quality lies in the middle of this horizontal line.
The analysis given above can be repeated for internal energy and enthalpy
with the following results:
(3–6)
(3–7)
All the results are of the same format, and they can be summarized in a sin-
gle equation as
where yis v,u, or h. The subscript “avg” (for “average”) is usually dropped
for simplicity. The values of the average properties of the mixtures are
always betweenthe values of the saturated liquid and the saturated vapor
properties (Fig. 3–37). That is,
Finally, all the saturated-mixture states are located under the saturation
curve, and to analyze saturated mixtures, all we need are saturated liquid
and saturated vapor data (Tables A–4 and A–5 in the case of water).
yfyavgyg
yavgyfxyfg
havghfxhfg¬¬ 1 kJ>kg 2
uavgufxufg¬¬ 1 kJ>kg 2
x
vavgvf
vfg
vavgvfxvfg¬¬ 1 m^3 >kg 2
vavg 11 x 2 vfxvg
mfmtmg¡mtvavg 1 mtmg 2 vfmgvg
Vmv¡mtvavgmfvfmgvg
VVfVg
130 | Thermodynamics
vg
v f
Saturated liquid
Saturated vapor
Saturated
liquid–vapor
mixture
≡
vavg
FIGURE 3–35
A two-phase system can be treated as a
homogeneous mixture for convenience.
P or T
v avg – v f
AB
AB
AC
x =
C
vfg
vf vavg vg v
FIGURE 3–36
Quality is related to the horizontal
distances on P-vand T-vdiagrams.