252 | Thermodynamics
Thus,
and
Therefore, after 30 min there is 0.6 kg water (liquid vapor) left in the
pressure cooker.
Discussion Note that almost half of the water in the pressure cooker has
evaporated during cooking.
m 2
V
v 2
0.006 m^3
0.01 m^3 /kg
0.6 kg
v 2 0.001 1 0.009 21 1.0040.001 2 m^3 /kg0.010 m^3 /kg
One of the most fundamental laws in nature is the first law of thermody-
namics,also known as the conservation of energy principle,which pro-
vides a sound basis for studying the relationships among the various forms
of energy and energy interactions. It states that energy can be neither created
nor destroyed during a process; it can only change forms.
The energy content of a fixed quantity of mass (a closed system) can be
changed by two mechanisms:heat transfer Qand work transfer W. Then the
conservation of energy for a fixed quantity of mass can be expressed in rate
form as
(5–47)
where Q
.
Q
.
net,inQ
.
inQ
.
outis the net rate of heat transfer to the system
(negative, if from the system),W
.
W
.
net,outW
.
outW
.
inis the net power
output from the system in all forms (negative, if power input) and dEsys/dtis
the rate of change of the total energy content of the system. The overdot
stands for time rate. For simple compressible systems, total energy consists
of internal, kinetic, and potential energies, and it is expressed on a unit-mass
basis as
(5–48)
Note that total energy is a property, and its value does not change unless the
state of the system changes.
An energy interaction is heatif its driving force is a temperature differ-
ence, and it is workif it is associated with a force acting through a distance,
as explained in Chap. 2. A system may involve numerous forms of work, and
the total work can be expressed as
(5–49)
where Wshaftis the work transmitted by a rotating shaft,Wpressureis the work
done by the pressure forces on the control surface,Wviscousis the work done
WtotalWshaftWpressureWviscousWother
eukepeu
V^2
2
gz
Q
#
W
#
dEsys
dt
¬or¬Q
#
W
#
d
dt
(^)
sys
re¬dV
TOPIC OF SPECIAL INTEREST General Energy Equation
This section can be skipped without a loss in continuity.