Potential energy is also a form of mechanical energy, and thus it can be
converted to work entirely. Therefore, the exergyof the potential energy of a
system is equal to the potential energy itself regardless of the temperature
and pressure of the environment (Fig. 8–5). That is,
Exergy of potential energy: (8–2)
where gis the gravitational acceleration and zis the elevation of the system
relative to a reference level in the environment.
Therefore, the exergies of kinetic and potential energies are equal to them-
selves, and they are entirely available for work. However, the internal energy u
and enthalpy hof a system are not entirely available for work, as shown later.
xpepegz¬¬ 1 kJ>kg 2
426 | Thermodynamics
m
Wmax = mgz
z
⋅
⋅ ⋅
FIGURE 8–5
The work potentialor exergyof
potential energy is equal to the
potential energy itself.
EXAMPLE 8–1 Maximum Power Generation by a Wind Turbine
A wind turbine with a 12-m-diameter rotor, as shown in Fig. 8–6, is to be
installed at a location where the wind is blowing steadily at an average veloc-
ity of 10 m/s. Determine the maximum power that can be generated by the
wind turbine.
Solution A wind turbine is being considered for a specified location. The max-
imum power that can be generated by the wind turbine is to be determined.
Assumptions Air is at standard conditions of 1 atm and 25°C, and thus its
density is 1.18 kg/m^3.
Analysis The air flowing with the wind has the same properties as the stag-
nant atmospheric air except that it possesses a velocity and thus some
kinetic energy. This air will reach the dead state when it is brought to a com-
plete stop. Therefore, the exergy of the blowing air is simply the kinetic
energy it possesses:
That is, every unit mass of air flowing at a velocity of 10 m/s has a work
potential of 0.05 kJ/kg. In other words, a perfect wind turbine will bring the
air to a complete stop and capture that 0.05 kJ/kg of work potential. To
determine the maximum power, we need to know the amount of air passing
through the rotor of the wind turbine per unit time, that is, the mass flow
rate, which is determined to be
Thus,
This is the maximum power available to the wind turbine. Assuming a con-
version efficiency of 30 percent, an actual wind turbine will convert 20.0 kW
to electricity. Notice that the work potential for this case is equal to the
entire kinetic energy of the air.
Discussion It should be noted that although the entire kinetic energy of the
wind is available for power production, Betz’s law states that the power output
of a wind machine is at maximum when the wind is slowed to one-third of its
initial velocity. Therefore, for maximum power (and thus minimum cost per
Maximum powerm# 1 ke 2 1 1335 kg>s 21 0.05 kJ>kg 2 66.8 kW
m
#
rAVr
pD^2
4
V 1 1.18 kg>m^32
p 1 12 m 22
4
1 10 m>s 2 1335 kg>s
ke
V^2
2
1 10 m>s 22
2
a
1 kJ>kg
1000 m^2 >s^2
b0.05 kJ>kg
10 m/s
FIGURE 8–6
Schematic for Example 8–1.