452 | Thermodynamics
(b) The reversible work, which represents the minimum work input Wrev,inin
this case, can be determined from the exergy balance by setting the exergy
destruction equal to zero,
Net exergy transfer Exergy Change
by heat, work, and mass destruction in exergy
since KE PE 0 and V 2 V 1. Noting that T 0 (S 2 S 1 ) T 0 Ssystem
19.6 Btu, the reversible work becomes
Therefore, a work input of just 1.0 Btu would be sufficient to accomplish
this process (raise the temperature of air in the tank from 70 to 130°F) if all
the irreversibilities were eliminated.
Discussion The solution is complete at this point. However, to gain some
physical insight, we will set the stage for a discussion. First, let us deter-
mine the actual work (the paddle-wheel work Wpw) done during this process.
Applying the energy balance on the system,
Net energy transfer Change in internal, kinetic,
by heat, work, and mass potential, etc., energies
since the system is adiabatic (Q0) and involves no moving boundaries
(Wb0).
To put the information into perspective, 20.6 Btu of work is consumed
during the process, 19.6 Btu of exergy is destroyed, and the reversible work
input for the process is 1.0 Btu. What does all this mean? It simply means
that we could have created the same effect on the closed system (raising its
temperature to 130°F at constant volume) by consuming 1.0 Btu of work
only instead of 20.6 Btu, and thus saving 19.6 Btu of work from going to
waste. This would have been accomplished by a reversible heat pump.
To prove what we have just said, consider a Carnot heat pump that absorbs
heat from the surroundings at T 0 530 R and transfers it to the air in the
rigid tank until the air temperature Trises from 530 to 590 R, as shown in
Fig. 8–39. The system involves no direct work interactions in this case, and
the heat supplied to the system can be expressed in differential form as
The coefficient of performance of a reversible heat pump is given by
COPHP
dQH
dWnet,in
1
1 T 0 >T
dQHdUmcv dT
Wpw,in¢U 20.6 Btu¬¬ 3 from part 1 b 24
EinEout¬¬ ¢Esystem
1.0 Btu
1 20.619.6 2 Btu
1 2 lbm 21 0.172 Btu>lbm#°F 21130 702 °F19.6 Btu
Wrev,inmcv 1 T 2 T 12 T 01 S 2 S 12
1 U 2 U 12 T 01 S 2 S 12
1 E 2 E 12 P 01 V 2 V 12 Q
0
T 01 S 2 S 12
Wrev,inX 2 X 1
XinXout¬ Xdestroyed ¢Xsystem
AIR
70 °F→ 130 °F
Ambient air
70 °F
Wnet,in = 1 Btu
Reversible
heat pump
19.6 Btu
20.6 Btu
FIGURE 8–39
The same effect on the system can be
accomplished by a reversible heat
pump that consumes only 1 Btu of
work.
0 (reversible)
⎭⎪⎬⎪⎫ → ⎭⎪⎬⎪⎫
⎭⎪⎪⎪⎬⎪⎪⎪⎫
⎭⎪⎬⎪⎫ ⎭⎪⎬⎪⎫