external to the system. A second-law analysis of these cycles reveals where
the largest irreversibilities occur and where to start improvements.
Relations for exergyand exergy destructionfor both closed and steady-
flow systems are developed in Chap. 8. The exergy destruction for a closed
system can be expressed as
(9–30)
where Tb,inand Tb,outare the temperatures of the system boundary where
heat is transferred into and out of the system, respectively. A similar relation
for steady-flow systems can be expressed, in rate form, as
(9–31)
or, on a unit–mass basis for a one-inlet, one-exit steady-flow device, as
(9–32)
where subscripts iand edenote the inlet and exit states, respectively.
The exergy destruction of a cycleis the sum of the exergy destructions of
the processes that compose that cycle. The exergy destruction of a cycle can
also be determined without tracing the individual processes by considering
the entire cycle as a single process and using one of the relations above.
Entropy is a property, and its value depends on the state only. For a cycle,
reversible or actual, the initial and the final states are identical; thus sesi.
Therefore, the exergy destruction of a cycle depends on the magnitude of
the heat transfer with the high- and low-temperature reservoirs involved and
on their temperatures. It can be expressed on a unit–mass basis as
(9–33)
For a cycle that involves heat transfer only with a source at THand a sink at
TL, the exergy destruction becomes
(9–34)
The exergies of a closed system fand a fluid stream cat any state can be
determined from
(9–35)
and
(9–36)
where subscript “0” denotes the state of the surroundings.
c 1 hh 02 T 01 ss 02
V^2
2
gz¬¬ 1 kJ>kg 2
f 1 uu 02 T 01 ss 02 P 01 vv 02
V^2
2
gz¬¬ 1 kJ>kg 2
xdestT 0 a
qout
TL
qin
TH
b¬¬ 1 kJ>kg 2
xdestT 0 aa
qout
Tb,out
a
qin
Tb,in
b¬¬ 1 kJ>kg 2
XdestT 0 sgenT 0 asesi
qin
Tb,in
qout
Tb,out
b¬¬ 1 kJ>kg 2
X
#
destT 0 S
#
genT 01 S
#
outS
#
in^2 T 0 aa
out
m#sa
in
m#s
Q
#
in
Tb,in
Q
#
out
Tb,out
b¬¬ 1 kW 2
T 0 c1S 2 S 12 sys
Qin
Tb,in
Qout
Tb,out
d¬¬ 1 kJ 2
XdestT 0 SgenT 01 ¢SsysSinSout 2
528 | Thermodynamics