Chemistry of Essential Oils

(Tuis.) #1

464 THE CHEMISTRY OF ESSENTIAL OILS


Specific gravity .......... 0-875
Optical rotation + 13°
Refractive index 1*4693
Acid number .......... 6



  • 1
    Ester value 28-2
    A sample examined by Schimmel & Co.
    1
    had the following characters :—
    Specific gravity 0-871
    Optical rotation + 32° 54'
    Refractive index 1'4887
    Acid value .......... O'J
    Ester „ 20-4
    The oil consisted almost entirely of terpenes, of which /?-pinener
    limonene, and dipentene were detected with certainty. No other con-
    stituent has been identified.


OIL OF HEERIA PANIC ULOSA.

The berries of Heeria Paniculosa, a plant indigenous to Zuzulandr
known to the natives as Isifeku, yield from 4*5 to 6 per cent, of essen-
tial oil, which has been examined by Juritz.^2 A sample examined in
the Imperial Institute Laboratories had the following characters :—


Specific gravity 0'852
Optical rotation + 3'75°
Ester value 4'2
Acid value 1-6
„ „ (after acetylatioii) 14*8
The oil consists mainly of terpenes.

BURSERACLVE.

OIL OF MYRRH.

Myrrh is an oleo-resinous substance obtained as a secretion in the
parenchyma of the bark of various species of Commiphora. The so-
called true myrrh, or Herabol myrrh, is collected principally in Arabia
and Somaliland, whilst Bisabol myrrh, or bdellium, occurs as an ad-
mixture of true myrrh, especially when collected in Somaliland, and is
identical or closely related to Indian bdellium.
Herabol Myrrh is chiefly derived from Commiphora myrrha, and
yields from 3 to 10 per cent, of a thick, yellow essential oil, having the
following characters :—


Specific gravity 0-985 to 1-045
Optical rotation - 30° „ - 90°
Refractive index 1-5180 „ 1-5280
Acid value 1 „ 8
Ester ,„15 „ 45
„ „ (after acetylation) 30 „ 70
It is soluble with, at most, slight turbidity, in 10 volumes of 90 per
cent, alcohol.
Lewinsohn
3
emphasises that the composition of myrr h oil differs
according to the origin of the resin, the method of production, and the
age. He believes that distillers add small quantities of alkali to tl^e


1
Report, April (1913), 86.
2
Chemical News, 1920,120, 277.
3
Arch, der Pharm., 244 (1906), 412.
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