Chemistry of Essential Oils

(Tuis.) #1

88 THE CHEMISTEY OF ESSENTIAL OILS


Albany and Uitenhaage and Fort Beaufort Divisions, at an altitude
of 1 to 3000 ft.
Oil from Elionurm tripsacoides has been examined by Umney, the
yield being about 0*1 per cent. It was yellow in colour, and had an
odour somewhat resembling vetivert. It gave a reddish-violet colour
with ferric chloride, but only contained traces of a phenol, probably
eugenol.
The characters of the oil were as follows:—
Specific gravity
Optical rotation .....
Ester number
Saponification number (after acetylation)

0*976


- 10


10° 5'


42


The boiling-point of the oil was very high, indicating the presence of
a sesquiterpene as the chief constituent.
The following figures are the result of fractionation :—
Portion distilling below 275° C.. nil.
280°
290°
300°
310°
320°
325°
above 325°

2 per cent.
14
42
50
56
68
32

PALM/E.


OIL OF SAW PALMETTO.

The fruits of the palm, Sabal serrulata, which is found in the
Southern United States, especially in Florida, have been stated to yield
about 12 per cent, of essential oil having the following characters :—
Specific gravity 0-868 at 20°
Optical rotation 0°
Refractive index 1
4275
The oil is probably not a true essential oil, but the product of reaction
between the free fatty acids of the fruits and the alcohol in which they
had been kept. According to Shermann and Briggs



  • the oil contains
    free caproic, caprylic, lauric, palmitic, and oleic acids, together with
    about 37 per cent, of the ethyl esters of these acids.


OIL OF COCO NUT.
A minute quantity of essential oil is obtained by distillation from
crude fatty oil of coco nut, Cocos nucifera.
The otf contains^2 methyl- heptyl - carbonyl, CH 3. CH(OH)C 7 H 15 ,
methyl - nonyl - carbinol, CH 3. CH(OH)C 9 H 19 , methyl - heptyl - ketone,
methyl-nonyl-ketone, and methyl-undecyl-ketone.


OIL OF EL^IS GUINEENSIS.
Salway^3 has examined the essential oil of palm kernels, the fruit of
Elais guineensis.
The oil has the following characters :—
^Pharm. Arch., 2 (1899), 101.
*Comptess rendus, 150 (1910), 1013; 151(1910), 697.
Jour. Chem. Soc. (1917), 407.

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