216 MECHANICAL ENGINEERING PRINCIPLES
Table 19.1
Latent heat of Melting
fusion (kJ/kg) point (°C)
Mercury 11.8 − 39
Lead 22 327
Silver 100 957
Ice 335 0
Aluminium 387 660
Latent heat of Boiling
vaporisation (kJ/kg) point (°C)
Oxygen 214 − 183
Mercury 286 357
Ethyl alcohol 857 79
Water 2257 100
Quantity of heat required,
Q=mL=12 kg×335 kJ/kg
=4020 kJor 4 .02 MJ
Problem 11. Calculate the heat required to
convert 5 kg of water at 100°Cto
superheated steam at 100°C. Assume the
latent heat of vaporisation of water is
2260 kJ/kg.
Quantity of heat required,
Q=mL=5kg×2260 kJ/kg
=11300 kJor 11 .3MJ
Problem 12. Determine the heat energy
needed to convert 5 kg of ice initially at
− 20 °C completely to water at 0°C. Assume
the specific heat capacity of ice is
2100 J/(kg °C) and the specific latent heat of
fusion of ice is 335 kJ/kg.
Quantity of heat energy needed,
Q=sensible heat+latent heat.
The quantity of heat needed to raise the tempera-
ture of ice from− 20 °Cto0°C, i.e. sensible heat,
Q 1 =mc(t 2 −t 1 )
=5kg×2100 J/(kg°C)×( 0 −− 20 )°C
=( 5 × 2100 × 20 )J=210 kJ
The quantity of heat needed to melt 5 kg of ice at
0 °C,
i.e. the latent heat,
Q 2 =mL=5kg×335 kJ/kg=1675 kJ
Total heat energy needed,
Q=Q 1 +Q 2 = 210 + 1675 =1885 kJ
Problem 13. Calculate the heat energy
required to convert completely 10 kg of
water at 50°C into steam at 100°C, given
that the specific heat capacity of water is
4200 J/(kg°C) and the specific latent heat of
vaporisation of water is 2260 kJ/kg.
Quantity of heat required=sensible heat+latent
heat.
Sensible heat,Q 1 =mc(t 2 −t 1 )
=10 kg×4200 J/(kg°C)
×( 100 − 50 )°C=2100 kJ
Latent heat, Q 2 =mL=10 kg×2260 kJ/kg
=22600 kJ
Total heat energy required,
Q=Q 1 +Q 2 =( 2100 + 22600 )kJ
=24700 kJor 24 .70 MJ
Problem 14. Determine the amount of heat
energy needed to change 400 g of ice,
initially at− 20 °C, into steam at 120°C.
Assume the following:
latent heat of fusion of ice=335 kJ/kg,
latent heat of vaporisation of
water=2260 kJ/kg, specific heat capacity of
ice= 2 .14 kJ/(kg°C), specific heat capacity
of water= 4 .2 kJ/(kg°C) and specific heat
capacity of steam= 2 .01 kJ/(kg°C).
The energy needed is determined in five stages:
(i) Heat energy needed to change the temperature
of ice from− 20 °Cto0°C is given by:
Q 1 =mc(t 2 −t 1 )
= 0 .4kg× 2 .14 kJ/(kg°C)×(0–− 20 )°C
= 17 .12 kJ