Analytical Chemistry

(Chris Devlin) #1

Table 8.1 Techniques based on atomic spectrometry


Spectrometric technique Radiation process Means of excitation Sample container/ medium Monochromator


arc/spark emission emission electric arc/spark carbon or graphite electrode diffraction grating or prism


laser microprobe emission emission laser original sample material diffraction grating


glow discharge emission emission glow discharge lamp machined sample disc diffraction grating


plasma emission emission electromagnetic
induction


gas plasma diffraction grating

atomic absorption absorption UV/visible radiation flame or heated rod/ furnace diffraction grating or prism


atomic fluorescence fluorescence emission UV/visible radiation flame or heated rod/ furnace filter


flame photometry (flame
atomic emission)


emission flame flame diffraction grating, prism or
filter

X-ray fluorescence fluorescence emission X-radiation cell single crystal diffractor


plasma mass spectrometry n/a electromagnetic
induction


gas plasma magnetic field
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