Wine Chemistry and Biochemistry

(Steven Felgate) #1

9E Health-Promoting Effects of Wine Phenolics 581


silencing at telomeres, DNA repair, and ribosomal DNA recombination (Guar-


ente 1999; Imai et al. 2000). Caloric restriction has been shown to extend life


span through activation of the silencing information regulator 2 (Sir2) gene inSac-


charomyces cerevisiae(Lin et al. 2000) andCaenorhabditis elegans(Tissenbaum


and Guarente 2001). The human homologof Sir2, SIRT1, is a p53 deacetylase


that promotes cell survival by negatively regulating the p53 tumor suppressor (Luo


et al. 2001; Vaziri et al. 2001). Inducing SIRT1 expression by caloric restriction


promotes long-term survival of mammalian cells (Cohen et al. 2004). Recently it


has been shown that SIRT1 controls the gluconeogenesis/glycolytic pathway in the


liver in response to fasting signals through the transcriptional coactivator of PGC-1


(Rodgers et al. 2005), suggesting a role for SIRT1 in energy metabolism, diabetes,


and life span. Thus, the use of molecules that trigger SIRT1 activity, mimicking the


effect of caloric restriction, would allow individuals to eat normally while the body


responds as though food were in short supply. Different plant polyphenols have been


found to stimulate SIRT1 activity; these include quercetin, piceatannol, and resver-


atrol (de Boer et al. 2006; Howitz et al. 2003). These and other compounds were


found to have a chemical structure similar to that of thetransstilbene ring. Thus, the


transstilbene resveratrol showed the highest stimulation of SIRT1 activity (Howitz


et al. 2003). Resveratrol has since been demonstrated to effectively extend life span


in different species, includingS. cerevisiae(Howitz et al. 2003),C. elegans,andthe


fruit flyDrosophila melanogaster(Wood et al. 2004), an effect that is dependent on


the Sir2 gene. In mammals, resveratrol has been shown to exert a protective effect


in several disease models, including cancer and diabetes (Garvin et al. 2006; Su
et al. 2006). The SIRT1 pathway also improves health and survival in mice on high-


calorie diets (Baur et al. 2006) and protects against neurodegeneration in mouse


models of Alzheimer’s disease and amyotrophic lateral sclerosis (Kim et al. 2007).


The amount of resveratrol in grapes and red wine, however, is relatively low and


depends on several strain-related and environmental factors, which together with


the low bioavailability of resveratrol in mammals, its low solubility, and sensitivity


to light and oxidation (Yang et al. 2007), may limit the achievement of target plasma


concentrations from normal food ingestion. Also, although it has been shown that


polyphenols protect against several pathological processes associated with aging


and have remarkable effects mimicking caloric restriction in vitro and in animal


models, it is not known whether resveratrol or other SIRT1 activators can extend life


span in humans. Further proof that a drug extends life span would require difficult,


extended clinical trials. Nevertheless, this promising effect of resveratrol along with


the other cardioprotective effects of wine polyphenols support the contention that


moderate wine consumption is health promoting.


The beneficial effects of wine may not be attributable to a single polyphenol


but rather to the complex mixture of polyphenols it contains. There is evidence


that antioxidant properties underlie most of the effects of wine, but at the same


time, certain effects cannot be mimicked by common dietary antioxidants. Although


polyphenols are not apanacea, those present in red grape and its derivatives appear


to exert beneficial effects on health.

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