Wine Chemistry and Biochemistry

(Steven Felgate) #1

64 A.J. Mart ́ınez-Rodr ́ıguez and E. Pueyo


3A.3 Foaming Properties


The most important sensorial characteristics of sparkling wines include, undoubt-


edly, the foaming properties perceived by the consumer when serving the sparkling


wine and also when drinking it.


A quality foam can be defined as one that causes a slow release of CO 2 ,inring


shapes from the depths of the liquid, with small bubbles that contribute to the for-


mation of a crown over the surface of the wine, covering it completely, with bubbles


two or three rows deep. The permanence of the foam on the surface of the wine


depends on a balance between the rate of foam formation and the rate at which the


bubbles making up this layer are destroyed.


A tasting card has been designed that can be used to evaluate the foaming


quality of a sparkling wine objectively (Obiols et al. 1998). However, it is also


important to have instrumental techniques that can be used to obtain a quantifi-


able value for foam quality, to be able to compare sparkling wines and also to be


able to correlate these foaming properties with the wines’ physical and chemical


characteristics, in order to establish which ofthese variables affect these properties.


With this knowledge, different technological aspects of the production process of


sparkling wines could be modified with the objective of improving their foaming


qualities.


The methods reported in the literature and used to quantify the foaming prop-


erties of sparkling wines can be classified into methods based on measuring the


kinetics of CO 2 discharging, gas sparging methods and image analysis methods.
The method of gas discharging kinetics (Maujean et al. 1988) involves studying


the time course of the mass quantification of the CO 2 discharged spontaneously


from the bottle. When all the free CO 2 has been discharged, the bottle is shaken to


quantify the so-called provoked CO 2.


Gas sparging methods are those most used in the past and still used today, and are


based on the procedure developed by Bikerman (1938). This essentially consists of


making a jet of gas pass at a controlled speed through a volume of wine to generate


a foam. Based on this method, experiments have been carried out with very simple


equipment made in the laboratory, that can be used to measure the height of foam


reached and the time it takes for this foam to collapse after the CO 2 jet has stopped


(Edward et al. 1982; Pueyo et al. 1995). The advantage of this method over that


described previously is that it can even be used to evaluate the foaming capacities


of still wines. In sparkling wine production it is very important since it permits


evaluation of the foaming characteristics of the base wines used to elaborate the


sparkling wines.


Later, Maujean et al. (1990) designed automated equipment to measure the foam-


ing properties of wines, based on Bikerman’s principle, called the Mosalux. This


equipment uses a photoelectric cell to record the height reached by the foam. It


incorporates a personal computer that can be used to control the experiments and,


also, for data acquisition. The foaming properties measured by Mosalux are HM or


maximum height of the foam or foaming power, HS, or stable height of the foam
with time and, TS, or stability time afterstopping the gas flow. This equipment

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