Quantum Mechanics for Mathematicians

(lily) #1

The position space wavefunctions can be recovered from the Fourier inversion
formula


ψ(q,t) =

1

2 π


R^2

eip·qψ ̃(p,t)d^2 p

Since, in the momentum space representation, the momentum operator is
the multiplication operator


Pψ ̃(p) =pψ ̃(p)

an eigenfunction for the Hamiltonian with eigenvalueEwill satisfy


(
|p|^2
2 m

−E

)

ψ ̃(p) = 0

ψ ̃(p) can only be non-zero ifE=|p|


2
2 m, so free particle solutions of energyEwill
thus be parametrized by distributions that are supported on the circle


|p|^2 = 2mE

p 1

p 2

p=


2 mE

θ

Figure 19.1: Parametrizing free particle solutions of Schr ̈odinger’s equation via
distributions supported on a circle in momentum space.


Going to polar coordinatesp= (pcosθ,psinθ), such solutions are given by

distributionsψ ̃(p) of the form


ψ ̃(p) =ψ ̃E(θ)δ(p^2 − 2 mE)
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