The Foundations of Chemistry

(Marcin) #1

EXAMPLE 1-10 Percentage


U.S. pennies made since 1982 consist of 97.6% zinc and 2.4% copper. The mass of a partic-
ular penny is measured to be 1.494 grams. How many grams of zinc does this penny contain?


Plan
From the percentage information given, we may write the required unit factor


Solution


__? g zinc1.494 g sample1.46 g zinc

The number of significant figures in the result is limited by the three significant figures in
97.6%. Because the definition of percentage involves exactly100 parts, the number 100 is known
to an infinite number of significant figures.


You should now work Exercises 59 and 60.


DENSITY AND SPECIFIC GRAVITY


In science, we use many terms that involve combinations of different units. Such quanti-


ties may be thought of as unit factors that can be used to convert among these units. The
densityof a sample of matter is defined as the mass per unit volume:


density or D

Densities may be used to distinguish between two substances or to assist in identifying a
particular substance. They are usually expressed as g/cm^3 or g/mL for liquids and solids
and as g/L for gases. These units can also be expressed as gcm^3 , gmL^1 , and
gL^1 , respectively. Densities of several substances are listed in Table 1-8.


EXAMPLE 1-11 Density, Mass, Volume


A 47.3-mL sample of ethyl alcohol (ethanol) has a mass of 37.32 g. What is its density?


Plan


We use the definition of density.


Solution


D0.789 g/mL

You should now work Exercise 36.


37.32 g

47.3 mL

m

V

m

V

mass

volume

1-11


97.6 g zinc

100 g sample

97.6 g zinc

100 g sample

The intensive property densityrelates
the two extensive properties: massand
volume.

1-11 Density and Specific Gravity 31

See the Saunders Interactive
General Chemistry CD-ROM,
Screen 1.8, Density.

Mass

Density

Volume

Mass
Volume

h

(^66)
(^66)
(^66)
(^66)
(^6) g
Six materials with different densities.
The liquid layers are gasoline (top),
water (middle), and mercury (bottom).
A cork floats on gasoline. A piece of
oak wood sinks in gasoline but floats
on water. Brass sinks in water but
floats on mercury.

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