Concise Physical Chemistry

P1: OSO
ind JWBS043-Rogers September 24, 2010 12:57 Printer Name: Yet to Come

370 INDEX

Battery, 221

Benzene, 342

Benzoic acid, 68

Bimembrane, 167

Bimolecularity, 155

Binary solutions, 184

Body-centered cubic cell, 180

Bohr, 236, 264

Boiling point elevation, 188

Boltzmann 101, 108

Boltzmann constant, 9

Boltzmann distribution of molecular speeds,

158

Bond additivity, 306

Bond breaking, 350

Bond dissociation energies (BDE), 348,

355, 358

Bond energy, 65

Bond enthalpies, 306

Bond length, 292, 299

Bond making, 350

Bond moments, 296

dichloroethene isomers, 296

Bond strength, 292, 299

Born probability postulate, 252

Born, 237

Born-Haber cycle, 178–179

Bosons and Fermions, 278

Boyle, 1

Bragg’s law, 173

Bravais crystal systems, 176

Bravais lattices, 176

Breaking degeneracy, 259

Cadmium half-cell, 232

Calculated ionization potentials,

281

Calomel electrode, 229

Calorie, 54

Calorimeter, 104

Calorimetry, 56

Capacitance, 294

Capillary rise, 167

Carbon dioxide, 34, 86

free energy of formation, 87

Carbon disulfide, 91, 92

Carnot, 71

Carnot’s engine, 72

Cartesian space, 330

Cathode, 217, 223

Cell diagrams, 223

Cell reaction, 223

Central field approximation, 239

Cerium, 234

Chain reaction, 153, 345–346

initiation, 346

propagation, 346

termination, 346

Charge distribution, 241

Charles, 1

Chemical kinetics, 144

Chemical potential, 87

nonideal systems, 100, 102

pressure dependence, 87

temperature dependence, 88–89

Chemical reactions, 78, 79

Chloroform, 200

Clapeyron equation, 128

Classical harmonic oscillator, 288

Classical molecular modeling, 305

Clausius, 71

Clausius–Clapeyron equation, 128

Close packing, 171

Closed system, 41

Coexistance curve, 127

Colligative properties, 187, 194

Collision theory, 158

Combined gas law, 2, 12

Combined or scripted methods, 338

Combining enthalpy and entropy, 84

Combustion of C(gr) and CO(g), 59

Combustion, 92

free energy of, 92

of methane, 92

Components, 124

Components, phases, and degrees of

freedom, 124

Compound phase diagrams, 137

Compressibility factor, 20, 21, 28

calculated from the van der Waals

constants, 28

Computational chemical script, 338

Computational geometries, 177

Computational kinetics, 159

Computational statistical thermodynamics,

119

GAUSSIAN 03©C, 119

Computational thermochemistry, 100