- Choose the most correct option.
i. In the following resonating structures
A and B, the number of unshared
electrons in valence shell present on
oxygen respectively are
d.
a. 2, 4 b. 2, 6
c. 4, 6 d. 6, 4
ii. In the Wolf -Kishner reduction, alkyl
aryl ketones are reduced to alkyl
benzenes. During this change, ketones
are first converted into
a. acids b. alcohols
c. hydrazones d. alkenes
iii. Aldol condensation is
a. electrophilic substitution reaction
b. nucleophilic substitution reaction
c. elimination reaction
d. addition - elimination reaction
iv. Which one of the following has lowest
acidity?
a.
NO 2
COOH
Cl
COOH
OCH 3
COOH
COOH
v. Diborane reduces
a. ester group b. nitro group
c. halo group d. acid group
vi. Benzaldehyde does NOT show positive
test with
a. Schiff reagent
b. Tollens' ragent
c. Sodium bisulphite solution
d. Fehling solution
- Answer the following in one sentence
i. What are aromatic ketones?
ii. Is phenyl acetic acid an aromatic
carboxylic acid?
iii. Write reaction showing conversion of
ethanenitrile into ethanol.
iv. Predict the product of the following
reaction:
CH 3 CH 2 COOCH 3 i. AlHii. H^ (i-Bu)^2
3 O⊕
?
b.
c.
v. Name the product obtained by reacting
toluene with carbon monoxide and
hydrogen chloride in presence of
anhydrous aluminium chloride.
vi. Write reaction showing conversion of
Benzonitrile into benzoic acid.
vii. Name the product obtained
by the oxidation of
1,2,3,4-tetrahydronaphthalene with
acidified potassium permanganate.
viii.What is formalin?
C
O
C
O
(A) (B)
⊕
Exercises