http://www.ck12.org Chapter 23. Electrochemistry
23.1 Electrochemical Cells
Lesson Objectives
- Use the activity series to predict whether a given oxidation-reduction reaction will occur spontaneously.
- Describe the components and function of a galvanic cell.
- Describe how power is produced by lead-acid batteries, dry cell batteries, and fuel cells.
Lesson Vocabulary
- activity series: A ranking of various metals on their ability to lose electrons.
- galvanic cell: A cell in which two solutions are connected by a wire in order to facilitate the flow of electrons
and generate an electric current. - battery: A cell which employs oxidation-reduction reactions to generate a flow of electrons and supply
electricity. - lead-acid battery: A battery with two poles, one of lead and one of lead oxide, submerged in sulfuric acid
and separated by a barrier permeable to ions and water; typically used in cars. - dry cell battery: Contains a paste (often a mixture of ammonium chloride and manganese dioxide) that acts
as the positive electrode. - fuel cell: A cell that is able to produce an electric current directly from a chemical reaction; fuel cells
commonly operate on the platinum catalyzed reaction between hydrogen and oxygen gases to be used to
power vehicles.
Check Your Understanding
Recalling Prior Knowledge
- Write half reactions for the following redox process:
2 Na + Cl 2 →2 NaCl
What is being oxidized, and what is being reduced?
Introduction
Electrochemistry is the study of chemical processes that occur at the interface between an electron conductor, such
as a wire, and a solution of electrolytes, which is often simply an ionic substance dissolved in water. Electrochemical
processes involve a transfer of electrons between the wire and the solution. These reactions can be used to create
electrical power, to purify metals, and to carry out a number of useful chemical transformations.