The structure of a saturated, an unsaturated, and a
transunsaturated chemical bond is depicted inTable 12and inFigure 14.HH
|^|- C
- C–
|
|
HHHH
||- C =
C –H
|- C =
C –
|
HSaturated Fat Carbon-Carbon
Single-bond hydrogensCisFat
Carbon-Carbon
Double-bond hydrogens onsame sideTransFat
Carbon-Carbon
Double-bond hydrogens onopposite sidesTable 12. Depiction of saturated,cis-unsaturated, andtrans-unsaturated fats. RED hydrogens are on the same side of acis-doublebond and on the opposite sides of atrans-double bond.Cis-fats are bent. This bending causes the molecule to occupymore space and become more fluid. This is illustrated inFigure 14.CisfatTrans fatFigure 14.Cisfats are bent.Transfats are generally straight.Dietary Fat
Fat tastes good to most of us—it makes carbohydrate more
palatable. Fat is also relatively inexpensive.A small amount of fat is necessary in the diet. Diets that derive more than 30% of their calories from fat are
considered unhealthy, because excess dietary fat is associated withobesity, heart disease, stroke, and some cancers.Polyunsaturated fats are believedto be better for health thansaturated or hydrogenated fats. Dietsthat derive more than 10% oftheir calories from saturated fat are considered unhealthy.US fat consumption averages about 33% of total calories. Excess fat is much more of a public health problem than too
little.Requirements
Dietary fat is composed of triglycerides, phospholipids, sterols,
and other lipid-soluble components.Triglycerides are the major component of dietary fats. Triglycerides consist of a glycerol backbone and three fatty acid
chains, the latter of which are classified as saturated,cismonounsaturated,cis-polyunsaturated, andtrans-fatty acids.Monounsaturated fatty acids, saturated fatty acids, and
cholesterol can be synthesized by the body. They are not essential in the diet.Two polyunsaturated fatty acids are essential in the diet: linoleic
acid and alpha-linolenic acid.Eicosapentaenoic acid and docosahexaenoic acid, two fatty acids
derived from the elongation and desaturation of alpha-linolenic acid,are also of nutritional significance. Eicosapentaenoic acid and docosahexaenoic acid can be interconverted.Nutrition for Sports, Essentials of 77